Radioactive Decay and Half-Life
2. Half-Life
Learning outcomes
- I can define half-life.
- I can explain what happens during each half-life.
- I can determine the remaining quantity after several half-lives.
- I can interpret half-life graphs.
- I can compare isotopes with different half-lives.
Half-Life
Half-life is the time required for the number of undecayed radioactive nuclei in a sample to decrease to half of its previous value.
Half-life can also describe the time required for a radioactive sample's:
- activity
- corrected count rate
to decrease to half of its previous value.
The symbol for half-life is:
t₁/₂
Radioactive decay is random for individual nuclei, but when a sample contains a very large number of nuclei, its overall decay follows a predictable pattern.
What Happens During One Half-Life?
Suppose a sample begins with:
1000 radioactive nuclei
After one half-life, approximately half remain undecayed:
1000 → 500
After another half-life:
500 → 250
Then:
250 → 125
The sample does not lose the same number of nuclei during each half-life.
Instead, it loses the same fraction:
1/2 of the radioactive nuclei present at the beginning of that interval.
Successive Half-Lives
A useful pattern is:
| Number of Half-Lives | Fraction Remaining | Percentage Remaining |
|---|---|---|
| 0 | 1 | 100% |
| 1 | 1/2 | 50% |
| 2 | 1/4 | 25% |
| 3 | 1/8 | 12.5% |
| 4 | 1/16 | 6.25% |
| 5 | 1/32 | 3.125% |
| 6 | 1/64 | 1.5625% |
Each half-life multiplies the remaining amount by:
1/2
Half-Life Does Not Mean Half the Sample Disappears
When radioactive nuclei decay, they transform into other nuclei and emit radiation.
Therefore, saying:
"half the sample disappears"
is usually inaccurate.
Instead:
half of the original radioactive parent nuclei have decayed.
The daughter nuclei produced by the decay may still remain physically present in the sample.
Half-Life and Random Decay
Half-life does not tell us exactly when a particular nucleus will decay.
Suppose an isotope has a half-life of:
20 years
This does not mean every nucleus survives exactly 20 years and then decays.
Some nuclei may decay:
- almost immediately
- after 5 years
- after 19 years
- after 40 years
- after much longer
However, in a very large population, approximately half of the original radioactive nuclei are expected to remain after one half-life.
Half-Life Describes a Population
Consider one radioactive nucleus.
We cannot predict when it will decay.
Now consider:
10²⁰ radioactive nuclei
We still cannot predict which individual nuclei will decay.
However, we can predict very accurately how the population will change.
This gives us the important distinction:
individual decay → random
large population → statistically predictable
Calculating the Fraction Remaining
After n half-lives:
fraction remaining = (1/2)ⁿ
where:
n = number of half-lives
For example, after 3 half-lives:
fraction remaining = (1/2)³
= 1/8
Therefore:
12.5% remains
Calculating the Number Remaining
The expected number of radioactive nuclei remaining can be calculated using:
N = N₀(1/2)ⁿ
where:
- N = number remaining
- N₀ = initial number
- n = number of half-lives
Example: Number of Nuclei
A radioactive sample initially contains:
12,800 radioactive nuclei
After one half-life:
12,800 → 6400
After two:
6400 → 3200
After three:
3200 → 1600
Therefore:
1600 nuclei remain after three half-lives.
Using the equation:
N = 12,800(1/2)³
N = 12,800/8
N = 1600
Example: Four Half-Lives
A sample initially contains:
9600 radioactive nuclei.
After four half-lives:
N = 9600(1/2)⁴
N = 9600/16
N = 600 nuclei
Therefore:
6.25% remains.
Calculating Mass Remaining
The same method can be used when a question gives the mass of a pure radioactive isotope.
Suppose a sample initially contains:
80 g
of a radioactive isotope.
After one half-life:
80 g → 40 g
After two:
40 g → 20 g
After three:
20 g → 10 g
After four:
10 g → 5 g
Therefore, after four half-lives:
5 g of the original radioactive isotope remains.
The total physical mass of all decay products is a separate issue; half-life calculations normally track the amount of the radioactive parent isotope.
Example: Mass Calculation
A radioactive isotope has:
initial mass = 240 mg
After three half-lives:
240 → 120 → 60 → 30
Therefore:
30 mg remains
Alternatively:
m = 240(1/2)³
m = 240/8
m = 30 mg
Activity
The activity of a radioactive sample is the number of nuclear decays occurring per second.
The SI unit is the:
becquerel (Bq)
1 Bq means:
1 decay per second
Activity also decreases according to the isotope's half-life.
Activity After Several Half-Lives
Suppose:
initial activity = 6400 Bq
After one half-life:
6400 → 3200 Bq
After two:
3200 → 1600 Bq
After three:
1600 → 800 Bq
After four:
800 → 400 Bq
The same halving pattern applies.
Activity Equation
After n half-lives:
A = A₀(1/2)ⁿ
where:
- A = activity remaining
- A₀ = initial activity
- n = number of half-lives
Example: Activity
A radioactive source has an initial activity of:
4800 Bq
After five half-lives:
A = 4800(1/2)⁵
A = 4800/32
A = 150 Bq
Count Rate and Half-Life
A radiation detector may record count rate rather than activity directly.
If the experimental setup remains unchanged:
corrected count rate ∝ activity
Therefore, corrected count rate also decreases with the same half-life.
For example:
800 counts/min
→ 400 counts/min
→ 200 counts/min
→ 100 counts/min
This represents three half-lives.
Remember Background Radiation
Detector readings usually include:
source radiation + background radiation
Therefore:
corrected count rate = measured count rate − background count rate
Half-life should normally be determined from the corrected count rate, not from an uncorrected detector reading.
Example with Background Radiation
Suppose:
background = 30 counts/min
Initial measured rate:
830 counts/min
Corrected initial rate:
830 − 30 = 800 counts/min
Later, measured rate:
430 counts/min
Corrected:
430 − 30 = 400 counts/min
The source count rate has halved.
Therefore, the time between these readings represents:
one half-life
Half-Life Graphs
Radioactive decay produces an exponential decay curve.
The graph usually has:
x-axis → time
and:
y-axis → number of radioactive nuclei, activity, or corrected count rate
The curve:
- decreases rapidly at first
- becomes progressively less steep
- approaches zero
- does not suddenly reach zero after a particular number of half-lives
Why the Decay Graph Is Curved
Suppose the sample begins with:
8000 nuclei
During the first half-life:
8000 → 4000
Number decayed:
4000
During the second:
4000 → 2000
Number decayed:
2000
During the third:
2000 → 1000
Number decayed:
1000
The same fraction decays each time:
1/2
but the actual number decaying becomes smaller.
Therefore, the graph is curved rather than a straight line.
Constant Fraction, Not Constant Amount
This is one of the most important ideas in half-life calculations.
Radioactive decay does not normally mean:
−100 nuclei every hour
or:
−20 Bq every day
Instead, it means a constant fractional decrease over each half-life.
For example:
800 → 400 → 200 → 100 → 50
The decreases are:
−400
−200
−100
−50
The amount lost changes, but the fraction lost remains:
1/2
Finding Half-Life from a Graph
Suppose a graph begins at:
1000 Bq
First find half:
1000/2 = 500 Bq
Find where the decay curve reaches 500 Bq.
Suppose this occurs at:
8 hours
Therefore:
t₁/₂ = 8 hours
You can check by finding when the activity reaches:
250 Bq.
This should occur approximately another 8 hours later:
16 hours
A Reliable Graph Method
To determine half-life from a graph:
- Choose a convenient y-value on the curve.
- Divide that value by 2.
- Find both values on the graph.
- Read their corresponding times.
- Subtract the times.
For example:
600 Bq occurs at 4 h.
300 Bq occurs at 10 h.
Therefore:
t₁/₂ = 10 − 4
t₁/₂ = 6 h
You do not have to start at t = 0.
Example: Interpreting a Graph
Suppose a graph gives:
| Time | Activity |
|---|---|
| 0 days | 1600 Bq |
| 5 days | 800 Bq |
| 10 days | 400 Bq |
| 15 days | 200 Bq |
| 20 days | 100 Bq |
The activity halves every:
5 days
Therefore:
half-life = 5 days
Finding the Number of Half-Lives
Use:
number of half-lives = elapsed time / half-life
or:
n = t/t₁/₂
Suppose:
elapsed time = 24 hours
half-life = 6 hours
Then:
n = 24/6
n = 4 half-lives
Example: Combining Time and Decay
An isotope has:
half-life = 4 days
initial mass = 160 mg
How much remains after:
12 days?
First find the number of half-lives:
n = 12/4
n = 3
Then:
160 → 80 → 40 → 20
Therefore:
20 mg remains
Example: Activity After a Given Time
A source has:
initial activity = 12,000 Bq
half-life = 3 hours
Find its activity after:
9 hours.
Number of half-lives:
n = 9/3
n = 3
Activity:
12,000 → 6000 → 3000 → 1500
Therefore:
A = 1500 Bq
Finding Elapsed Time
A radioactive sample decreases from:
1600 Bq
to:
100 Bq
The sequence is:
1600 → 800 → 400 → 200 → 100
This is:
4 half-lives
If the half-life is:
6 hours
then:
time = 4 × 6
time = 24 hours
Finding the Original Quantity
Sometimes the final amount is given.
Suppose:
25 mg remains after 3 half-lives.
Work backwards by doubling:
25 → 50 → 100 → 200
Therefore:
initial mass = 200 mg
Percentage Remaining
The percentage remaining can be calculated:
percentage remaining = (1/2)ⁿ × 100%
For example, after 3 half-lives:
percentage = (1/2)³ × 100%
= 1/8 × 100%
= 12.5%
Percentage Decayed
If 12.5% remains, then:
percentage decayed:
= 100% − 12.5%
= 87.5%
Be careful to distinguish between:
percentage remaining
and:
percentage decayed
Example: Percentage Decayed
After four half-lives:
fraction remaining = 1/16
percentage remaining:
= 6.25%
Therefore:
percentage decayed:
= 100 − 6.25
= 93.75%
The Exponential Decay Equation
For times that are not exact whole numbers of half-lives, radioactive decay can be described using:
N = N₀e^(−λt)
where:
- N = number remaining
- N₀ = initial number
- λ = decay constant
- t = time
The equivalent activity equation is:
A = A₀e^(−λt)
These equations describe the smooth exponential decay curve.
Half-Life and Decay Constant
Half-life and decay constant are related:
t₁/₂ = 0.693/λ
or:
λ = 0.693/t₁/₂
where λ is the decay constant.
A large λ corresponds to:
short half-life
A small λ corresponds to:
long half-life
Example: Decay Constant
An isotope has:
t₁/₂ = 8 hours
Then:
λ = 0.693/8
λ ≈ 0.0866 h⁻¹
Comparing Isotopes
Different radioactive isotopes can have dramatically different half-lives.
Some decay extremely rapidly.
Others decay over:
- days
- years
- thousands of years
- millions or billions of years
Half-life is a characteristic property of a particular radioactive isotope.
Short Half-Life
An isotope with a short half-life has a relatively high probability of decay per unit time.
Therefore, a sample typically:
- loses activity rapidly
- produces many decays per unit time relative to the number of nuclei present
- becomes much less active relatively quickly
For the same number of radioactive nuclei, a shorter half-life generally corresponds to greater activity.
Long Half-Life
An isotope with a long half-life has a lower decay probability per unit time.
Therefore:
- individual nuclei are statistically more likely to survive longer
- activity decreases slowly
- radioactive material may persist for long periods
A long half-life does not mean the radiation itself is more penetrating.
Penetrating power depends mainly on the type and energy of radiation, not simply the half-life.
Comparing Two Isotopes
Suppose:
Isotope A: t₁/₂ = 2 hours
Isotope B: t₁/₂ = 20 hours
After 20 hours:
Isotope A has experienced:
20/2 = 10 half-lives
Fraction remaining:
1/1024
Isotope B has experienced:
20/20 = 1 half-life
Fraction remaining:
1/2
Therefore, isotope A decreases much more rapidly.
Comparing Decay Curves
On a graph:
Short half-life
The curve:
- falls steeply
- reaches half its initial value quickly
Long half-life
The curve:
- decreases more gradually
- takes longer to reach half its initial value
If two samples start with the same number of radioactive nuclei, the steeper decay curve represents the isotope with the:
shorter half-life
Half-Life and Activity
Activity is:
A = λN
where:
- A = activity
- λ = decay constant
- N = number of undecayed nuclei
Suppose two samples contain the same number of radioactive nuclei.
The isotope with the larger decay constant has:
- greater activity
- shorter half-life
The isotope with the smaller decay constant has:
- lower activity
- longer half-life
Half-Life Does Not Determine Radiation Type
An isotope's half-life does not tell us whether it emits:
- alpha
- beta
- gamma
For example, two isotopes may have similar half-lives but emit different forms or energies of radiation.
Half-life describes:
how rapidly a radioactive population decays
Radiation type describes:
what is emitted during the decay
These are different properties.
Half-Life Does Not Determine Penetration
A common misconception is:
long half-life = more penetrating radiation
This is incorrect.
Penetrating ability depends on radiation type and energy.
For example:
- alpha has low penetration
- beta has moderate penetration
- gamma has high penetration
regardless of whether the particular isotope has a relatively short or long half-life.
Why Different Half-Lives Are Useful
Different applications require different half-lives.
An isotope used as a medical tracer may need to remain radioactive long enough for:
- preparation
- administration
- imaging
but ideally not remain unnecessarily radioactive for a very long time.
By contrast, dating ancient materials requires isotopes with half-lives appropriate to the timescale being measured.
Carbon-14
Carbon-14 undergoes beta-minus decay.
Its half-life is approximately:
5730 years
This makes it useful for estimating the age of certain once-living materials over archaeological timescales.
The remaining carbon-14 decreases predictably over time.
Carbon-14 Example
Suppose a sample originally had a certain carbon-14 activity.
After:
5730 years
approximately:
1/2 remains
After:
11,460 years
approximately:
1/4 remains
After:
17,190 years
approximately:
1/8 remains
This predictable decrease can be used in radiometric dating.
Long-Lived Isotopes and Geological Dating
Very long-lived radioactive isotopes can be useful for investigating geological timescales.
For example, uranium isotopes can have half-lives measured in hundreds of millions or billions of years.
Such long half-lives allow radioactive decay to function as a natural clock over Earth's geological history.
Half-Life in Medicine
Radioactive isotopes used in medicine are selected partly according to half-life.
An appropriate isotope should often:
- remain active long enough to perform its function
- decay sufficiently quickly to limit prolonged unnecessary exposure
- emit radiation suitable for the intended procedure
Therefore, selecting an isotope involves balancing:
half-life + radiation type + radiation energy + chemical behaviour
Half-Life and Nuclear Waste
Half-life is also important when considering radioactive waste.
Short-lived isotopes may have relatively high activity initially but decrease substantially over shorter timescales.
Long-lived isotopes may remain radioactive for much longer.
Waste management therefore considers:
- half-life
- activity
- radiation type
- radiation energy
- chemical properties
- biological effects
Half-life alone does not determine overall hazard.
Half-Life Is Not the Same as "Safe Life"
After one half-life, the material has not become non-radioactive.
It still has approximately:
50% of its original radioactive nuclei
After five half-lives:
3.125% remains
Even after many half-lives, some radioactive nuclei can remain.
Therefore, there is no universal rule that a source becomes automatically "safe" after one or two half-lives.
Radioactive Material Does Not Reach Zero After a Fixed Number of Half-Lives
Mathematically, exponential decay approaches zero.
For example:
100%
→ 50%
→ 25%
→ 12.5%
→ 6.25%
→ 3.125%
→ 1.5625%
The expected fraction becomes progressively smaller.
For actual samples containing a finite number of nuclei, eventually the remaining radioactive nuclei will individually decay, but the ideal exponential model does not suddenly become zero after a fixed number of half-lives.
Problem-Solving Strategy
When solving half-life problems:
Identify the initial quantity
This could be:
- mass of radioactive isotope
- number of nuclei
- activity
- corrected count rate
Identify the half-life
For example:
t₁/₂ = 4 days
Find the elapsed time
For example:
t = 12 days
Calculate the number of half-lives
n = t/t₁/₂
Halve once for each half-life
or use:
remaining = initial × (1/2)ⁿ
Check your answer
The remaining amount should:
- decrease with time
- halve during each half-life
- never become negative
Worked Example
A radioactive isotope has:
initial activity = 9600 Bq
half-life = 6 hours
Find the activity after:
24 hours.
Number of half-lives:
n = 24/6
n = 4
Now halve four times:
9600 → 4800 → 2400 → 1200 → 600
Therefore:
A = 600 Bq
Worked Example: Finding Time
A sample decreases from:
320 mg
to:
20 mg
Sequence:
320 → 160 → 80 → 40 → 20
This represents:
4 half-lives
If:
t₁/₂ = 7 days
then:
t = 4 × 7
t = 28 days
Worked Example: Finding Half-Life
A source has an initial corrected count rate of:
1600 counts/min
After 18 hours:
200 counts/min
Determine the half-life.
Halving sequence:
1600 → 800 → 400 → 200
This is:
3 half-lives
Therefore:
t₁/₂ = 18/3
t₁/₂ = 6 hours
Worked Example: Comparing Isotopes
Isotope X has:
t₁/₂ = 4 days
Isotope Y has:
t₁/₂ = 12 days
Both begin with 8000 nuclei.
After 12 days:
Isotope X
Number of half-lives:
12/4 = 3
Remaining:
8000(1/2)³
= 1000 nuclei
Isotope Y
Number of half-lives:
12/12 = 1
Remaining:
8000(1/2)
= 4000 nuclei
Therefore, isotope X decays more rapidly because it has the shorter half-life.
Common Mistakes
Mistake: Saying half-life is the time for all nuclei to decay.
Half-life is the time for the expected number of undecayed nuclei to decrease by half.
Mistake: Subtracting the same amount during every half-life.
The quantity is multiplied by 1/2, not reduced by a fixed number.
Mistake: Halving the original quantity every time.
Each new half-life halves the remaining quantity.
Mistake: Saying an individual nucleus lives for exactly one half-life.
Individual decay is random.
Mistake: Forgetting to calculate how many half-lives have passed.
Use n = t/t₁/₂.
Mistake: Using uncorrected detector data.
Background radiation should normally be subtracted before determining half-life from count-rate data.
Mistake: Saying a short half-life means low activity.
For equal numbers of radioactive nuclei, a shorter half-life corresponds to a larger decay constant and greater activity.
Mistake: Saying a long half-life means more penetrating radiation.
Half-life and penetrating ability are different properties.
Key Terms
Half-life (t₁/₂) — time required for the expected number of undecayed nuclei or activity of a radioactive sample to fall to half its previous value.
Radioactive decay — spontaneous transformation of an unstable nucleus.
Parent nucleus — original unstable radioactive nucleus.
Daughter nucleus — nucleus produced by radioactive decay.
Activity — number of nuclear decays occurring each second.
Becquerel (Bq) — SI unit of activity; 1 Bq = 1 decay/s.
Count rate — number of radiation events detected per unit time.
Corrected count rate — detector count rate after background radiation has been subtracted.
Decay constant (λ) — measure of the probability of decay per unit time.
Exponential decay — decrease in which the rate of change depends on the amount remaining.
Background radiation — radiation present in the environment independently of the source being investigated.
Radiometric dating — determination of age using predictable radioactive decay.
Key Takeaways
- Half-life is the time required for the expected amount of radioactive parent material to decrease to half its previous value.
- The symbol for half-life is t₁/₂.
- Half-life can be applied to number of nuclei, activity, radioactive-isotope mass and corrected count rate.
- After one half-life, 50% remains.
- After two, 25% remains.
- After three, 12.5% remains.
- After four, 6.25% remains.
- Each half-life halves the quantity that is currently remaining.
- The same fraction decays during each half-life, not the same number.
- Individual nuclear decay is random.
- Half-life describes predictable statistical behaviour of large populations.
- Radioactive decay produces an exponential curve.
- The number of half-lives is n = t/t₁/₂.
- The expected remaining quantity can be calculated using N = N₀(1/2)ⁿ.
- Background radiation should be removed when interpreting detector count-rate data.
- Different isotopes have different characteristic half-lives.
- A shorter half-life means more rapid decay.
- A longer half-life means slower decay.
- Half-life does not determine whether radiation is alpha, beta or gamma.
- Half-life does not directly determine penetrating ability.
- The usefulness of a radioactive isotope depends partly on whether its half-life suits the intended application.
Check Your Understanding
- Define half-life.
- What percentage of a radioactive sample remains after one half-life?
- What fraction remains after three half-lives?
- What percentage remains after four half-lives?
- Explain why the same number of nuclei does not decay during every half-life.
- A sample begins with 6400 radioactive nuclei. How many are expected to remain after three half-lives?
- A radioactive isotope has an initial mass of 160 mg. How much of the parent isotope remains after five half-lives?
- A source begins with an activity of 8000 Bq. What is its expected activity after four half-lives?
- An isotope has a half-life of 6 hours. How many half-lives pass in 30 hours?
- A 320 mg sample has a half-life of 5 days. How much parent isotope remains after 20 days?
- A source's activity decreases from 2400 Bq to 300 Bq. How many half-lives have passed?
- If the half-life in Question 11 is 4 hours, how much time has passed?
- Explain how half-life can be determined from a decay graph.
- Why is a radioactive-decay graph curved rather than a straight line?
- Explain why background radiation should be subtracted when finding half-life from detector readings.
- Isotope A has a half-life of 2 hours and isotope B has a half-life of 20 hours. Which decays more rapidly? Explain.
- Explain why a longer half-life does not necessarily mean more penetrating radiation.
- A sample has a half-life of 10 years. Does this mean every nucleus decays after exactly 10 years? Explain.
- After six half-lives, what fraction and percentage of the original radioactive nuclei are expected to remain?
- A source has an initial corrected count rate of 6400 counts/min. After 15 hours it has fallen to 800 counts/min. Determine its half-life.